The ESP-07S is a bare ESP-chip, so you need some external parts to get it to work at all.
Some GPIO's need specific settings for running firmware and flash mode.
Roughly:
GPIO0 --> 3.3V run firmware
GPIO0 --> 0V flash mode after next reset/restart
GPIO15 --> 0V run firmware
GPIO2 --> 3.3V run firmware.
CH_PD --> 3.3V must be 3.3V for running the chip ("Enable").
On top put a 100nF ceramic capacitor from the Vcc pin to the gnd pin of the ESP as enar as possible.
For my circuits I put all needed pins together on a pinheader. maybe have a look at
https://www.letscontrolit.com/wiki/inde ... /IR-Remote
There is a schematic (pdf availlable beneath the shown schematics) that shows
the complete ESP circuit.
That page also describes the flashing.
Regards
Shardan